Tetraethylammonium Hydroxide CAS 77-98-5


Factory wholesale Tetraethylammonium Hydroxide CAS 77-98-5
- Appearance:Liquid
- Purity:99.8%
- Delivery:30days
- Sample Available:Available
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Name: Tetraethylammonium Hydroxide
CAS: 77-98-5
MOQ: 1KG
Directory Guidance on Tetraethylammonium Hydroxide
Chemical Structure
Basic Info:
Melting point | -98C |
Boiling point | 110 °C |
density | 1.023 g/mL at 25 °C |
refractive index | n20/D 1.422 |
Fp | 11 °C |
Product Introduction:
Tetraethylammonium hydroxide (TEAH) is a quaternary ammonium base compound of important industrial value with the chemical formula N(C₂H₅)₄ + OH⁻. As a strongly alkaline substance, it usually exists in the form of aqueous or methanol solutions with concentrations ranging from 20% to 40%, and appears colorless to yellowish transparent liquid. In its molecular structure, four ethyl groups form a stable tetrahedral configuration through nitrogen atoms. This unique spatial structure gives it strong nucleophile and solubility, especially in polar solvents, showing excellent dispersion. From the point of view of physical properties, the melting point of Tetraethylammonium Hydroxide is low, easy to absorb moisture, and with the increase of concentration, the viscosity of the solution will increase significantly. In terms of chemical properties, it can not only neutralize with acid to produce the corresponding quaternary ammonium salt, but also decompose under high temperature or light conditions to produce triethylamine, ethanol and other by-products, which puts forward strict requirements for its storage conditions.
Due to the strong alkali of Tetraethylammonium Hydroxide, its production equipment usually needs to use corrosion-resistant materials, such as polytetrafluoroethylene or special stainless steel, to avoid the introduction of impurities caused by equipment corrosion. It is worth noting that the compound is poor in solid state stability, easy to absorb carbon dioxide in the air to generate carbonate, so the industry is mostly stored and transported in solution form, and needs to be sealed under the protection of inert gas. In addition, the pH value of its aqueous solution can reach more than 13, which is significantly corrosive, and protective equipment should be worn during operation to avoid skin or mucous membrane contact.
From a thermodynamic point of view, the decomposition temperature of Tetraethylammonium Hydroxide is about 100-120℃, and the decomposition products include triethylamine, ethylene and water. This feature requires careful handling in high temperature applications. During storage, light will accelerate its decomposition, so it is usually recommended to store in a cool environment away from light. In terms of solubility, in addition to water and methanol, it also has good solubility in polar solvents such as ethanol and isopropyl alcohol, but in non-polar solvents such as n-hexane, the solubility is very low. This solution property provides an important basis for its application in different industrial scenarios. In addition, the electrical conductivity of Tetraethylammonium Hydroxide is strong, and its solution is often used as an electrolyte additive in the field of electrochemistry, which is closely related to the freely mobile quaternary ammonium cation in its molecular structure.
Nature and Specifications:
Item | Specification |
Product Name | Tetraethylammonium Hydroxide |
CAS No. | 77-98-5 |
Appearance | Liquid |
Shelf Life | 2 years |
Packing | As your requirements |
storage temp. | 2-8°C |
form | Solution |
color | colorless to yellow |
PH | >13 (H2O, 20°C) |
Water Solubility | SOLUBLE |
Product service:
- Certificate Of Analysis (COA)
- Material Safety Data Sheet (MSDS)
- Route of synthesis (ROS)
- Method of Aanlysis (MOA)
- Nuclear Magnetic Resonance (NMR)
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- Free Sample
- Factory audit
Tetraethylammonium Hydroxide has unique value in industrial applications. Its core advantage is the steric hindrance effect of strong alkalescence and quaternary ammonium cation, which can regulate the reaction path. In the field of organic synthesis, as a phase transfer catalyst, it can improve the rate and product selectivity of two phase reaction systems, and its catalytic effect is due to the solubilization effect and directional arrangement ability of quaternary ammonium cation. In addition, in the preparation of special structural polymers, it acts as a template agent, guides the monomer orientation through electrostatic action, accurately controls the polymer chain structure, and occupies an important position in the synthesis of polymer materials.
In the electronics industry, the application of Tetraethylammonium Hydroxide is refined. As the semiconductor manufacturing process develops towards the nanoscale, it has strict requirements on cleaning agents. Due to its high purity and low metal impurity content, this compound is used in wafer surface cleaning and etching processes. Its strong alkalinity can remove organic pollutants and metal ion residues without excessively corroding the substrate.
The catalytic field is another important application direction of Tetraethylammonium Hydroxide. In the petrochemical industry, it is used as an alkaline catalyst to participate in alkylation, isomerization and other reactions, especially in the preparation of high-octane gasoline groups, which can improve the reaction efficiency, and has better system compatibility and reduce side reactions compared with traditional inorganic alkali catalysts. In the production of biodiesel, it can effectively catalyze the transesterification reaction as a homogeneous catalyst, and can be recovered by acidification separation in the subsequent treatment. In the synthesis of fine chemicals, as an important part of chiral catalysts, it achieves stereoselective control through molecular recognition, which is of great significance for the synthesis of drug intermediates.
The product advantage of Tetraethylammonium Hydroxide is first reflected in its unique performance combination as a strong alkaline reagent. Compared with traditional inorganic bases, its alkalinity is close to that of sodium hydroxide, but it has better organic phase solubility, which is particularly important in reactions involving heterogeneous systems. The hydrophobic properties of quaternary ammonium cations enable them to transfer reactants across the phase interface, which is particularly critical in phase transfer catalysis. At the same time, the designability of its molecular structure provides the possibility for functional modification. By adjusting the length of the alkyl chain or introducing specific functional groups, derivative products that meet specific needs can be developed. This structure-performance controllability gives it a significant advantage in the development of customized chemicals.
This stability is derived from the precise control of the decomposition path in the production process. The decomposition reaction caused by high temperature or light is effectively suppressed by adding trace stabilizers. In addition, Tetraethylammonium Hydroxide low volatility reduces the risk of vapor exposure in the production environment. With the dedicated neutralization treatment system, environmentally friendly operation of the entire process can be achieved.
From the perspective of process economy, the comprehensive use cost of Tetraethylammonium Hydroxide has a competitive advantage. Although its unit mass price is higher than that of traditional inorganic bases, due to its high catalytic efficiency and low dosage, the actual use cost can be reduced by 20%-30%. In terms of recycling, the quaternary ammonium salt after the reaction can restore alkalinity through a simple regeneration process. This reusable feature is in line with the development trend of green chemistry. In terms of safety performance, its corrosiveness is lower than that of concentrated sodium hydroxide solution, and the matching neutralization reagent (such as dilute hydrochloric acid) is easy to obtain, which significantly reduces the difficulty of handling accidental leaks.
From the perspective of physical and chemical properties, Tetraethylammonium Hydroxide shows excellent system adaptability. The viscosity of its solution can be flexibly adjusted according to the concentration, which can meet the requirements of the spraying process for fluidity and the requirements of the dipping process for adhesion. It still maintains good fluidity under low temperature conditions, which makes it unique in industrial applications in cold regions. The adjustable conductivity has enabled it to achieve application breakthroughs in emerging fields such as fuel cell electrolytes and supercapacitor electrolytes. More importantly, its good compatibility with a variety of organic and inorganic materials means that there is no need for complex surface modification during the preparation of composite materials, which significantly simplifies the production process.
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Related References:
chemicalbook-Tetraethylammonium Hydroxide
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