Lithium Tetrachloroaluminate CAS 14024-11-4
High Quality Lithium Tetrachloroaluminate CAS 14024-11-4
- Appearance:Powder
- Purity:99.8%
- Delivery:30days
- Sample Available:Available
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Name: Lithium Tetrachloroaluminate
CAS: 14024-11-4
MOQ: 1KG
Directory Guidance on Lithium Tetrachloroaluminate
Chemical Structure
Basic Info:
Physical State | Solid |
Solubility | Solubility in water: Reacts violently |
Storage | Desiccate at room temperature |
Product Introduction:
Lithium Tetrachloroaluminate (AlCl4Li) is a white or colorless crystalline compound that often exists in the solid state. It is a lithium aluminate salt formed by the reaction of aluminum chloride and lithium salts, and has high solubility, especially in non-aqueous solvents such as benzene and chloroform. Due to its ionic properties, it is used as a catalyst or reagent in some organic reactions. It has a strong electronegativity and can react with water to produce hydrogen chloride gas, so it needs to be stored in a dry environment.
Its chemical structure is tetrahedral coordination, with aluminum atoms connected to four chloride ions and paired with lithium ions. Lithium Tetrachloroaluminate can form complexes with other compounds in solution and show certain reactivity. This makes it particularly important in some organic syntheses, such as the Friedel–Crafts reaction. It can also be used as a reagent in the preparation of other aluminum compounds or in organic synthesis.
In terms of physical properties, Lithium Tetrachloroaluminate has poor stability at high temperatures and is easily decomposed into lithium chloride and aluminum trichloride. This compound is usually white or colorless crystals with low melting and boiling points. It easily absorbs moisture in the air and is highly corrosive.
In addition, Lithium Tetrachloroaluminate plays a role in battery technology, catalyst research, and organic synthesis. In the research of lithium-ion batteries, it has shown certain application potential as an electrolyte or ion conductive material.
Nature and Specifications:
| Item | Specification |
| Product Name | Lithium Tetrachloroaluminate |
| CAS No. | 14024-11-4 |
| Appearance | Powder |
| Shelf Life | 2 years |
| Packing | As your requirements |
| Product Name: | Lithium Tetrachloroaluminate |
| Synonyms: | ithium aluminium chloride |
| CAS: | 14024-11-4 |
| MF: | AlCl4Li |
| MW: | 175.73 |
| EINECS: | 237-850-9 |
Product service:
- Certificate Of Analysis (COA)
- Material Safety Data Sheet (MSDS)
- Route of synthesis (ROS)
- Method of Aanlysis (MOA)
- Nuclear Magnetic Resonance (NMR)
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Lithium Tetrachloroaluminate (LiAlCl₄) is a lithium-containing organometallic compound with strong reactivity and a variety of useful chemical properties. It is widely used in many fields.
1. Organic synthesis field
As a strong Lewis acid, Lithium Tetrachloroaluminate is often used to catalyze organic synthesis reactions, especially in alkylation, acylation and nucleophilic substitution reactions. It can promote some reactions, such as reducing halogenated hydrocarbons, ketones and aldehydes to corresponding organic products in reduction reactions. In addition, it can also be used as a solvent or reaction medium to improve the efficiency and selectivity of certain reactions.
2. Polymer chemistry
In polymer chemistry, Lithium Tetrachloroaluminate is mainly used to catalyze polymerization reactions, especially in anionic polymerization. It can initiate polymerization reactions and control the molecular weight of polymers. It can also be used as a polymer modifier to improve the properties of polyolefins and other engineering plastics.
3. Lithium battery application
Lithium Tetrachloroaluminate has gradually attracted attention in the field of lithium batteries. As an electrolyte additive, it can improve the conductivity and cycle stability of batteries. It can also be used as a lithium source to help improve the capacity and performance of lithium batteries during the manufacturing process, and enhance the overall performance of the battery.
4. Catalysis and chemical reaction intermediates
As a Lewis acid catalyst, Lithium Tetrachloroaluminate can promote a variety of organic chemical reactions, including the formation or breakage of C-C bonds, nucleophilic substitution reactions, etc. It also plays an important role as a reaction intermediate in some complex organic syntheses, promoting the synthesis process of certain chemicals.
5. Environmental protection and energy fields
The potential of Lithium Tetrachloroaluminate in the fields of environmental protection and energy is being studied, especially in the capture and conversion of CO₂. It can participate in these reactions as a catalyst to help reduce greenhouse gas emissions. Its electrochemical properties also make it a research object for new energy storage materials, which may help improve battery energy density and cycle efficiency.
6. Medicinal chemistry and biomedicine fields
Although Lithium Tetrachloroaluminate is relatively rarely used in medicinal chemistry, it has potential value as a catalyst in the synthesis of some drugs. Especially when synthesizing complex organic molecules, it can provide a specific chemical environment to promote the efficient synthesis of certain drug molecules.
7. Other applications
In addition to the above fields, Lithium Tetrachloroaluminate also shows application prospects in syngas reaction catalysis and organic dechlorination reaction. It can be used as a catalyst to help improve reaction efficiency when synthesizing important chemicals such as ammonia and methanol. It can also be used to remove chlorine from organic compounds and has certain application potential in the field of environmental protection.
Strong Lewis Acid Properties: Lithium Tetrachloroaluminate is a strong Lewis acid that reacts effectively with Lewis bases, making it particularly useful in catalytic reactions and promoting a variety of organic synthesis reactions, such as esterification, Friedel-Crafts alkylation, and acylation reactions.
High Melting and Boiling Points: Lithium Tetrachloroaluminate has high melting and boiling points, making it stable under high temperature conditions and suitable for high temperature chemical reactions and material preparation.
Good Electrical Conductivity: It can provide good ionic conductivity under certain conditions, which makes it potentially useful in battery materials and capacitors.
Versatility: Lithium Tetrachloroaluminate has applications in multiple areas of chemistry and materials science, including catalysis, battery materials, capacitors, metal organic chemistry, materials science, and fine chemicals.
Easy Preparation: Lithium Tetrachloroaluminate can be prepared by relatively simple chemical synthesis methods, such as by direct reaction of lithium, aluminum, and chlorine or by reaction of aluminum chloride with lithium hydroxide.
Environmentally friendly: Compared with some other heavy metal catalysts, Lithium Tetrachloroaluminate has relatively low toxicity in the environment, so it may be a more environmentally friendly choice in some cases.
Improve reaction efficiency and selectivity: In catalytic reactions, Lithium Tetrachloroaluminate can improve the efficiency and selectivity of the reaction, thereby increasing the purity and yield of the product.
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Related References:
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1. For products ≤50kg, we recommend using express delivery, which is usually called DDU service (discounted, convenient).
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3. For products >500kg, we generally recommend shipping by sea, which is usually called FOB, CFR or CIF service (economical, safe).
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Our MOQ is 1kg. But usually we accept less quantity such as 100g on the condition that sample charge is 100% paid.
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